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English 15:04 Science & Tech

6 Times Scientists Were Wrong About the Periodic Table

SciShow · 107,615 views · Added 1 month ago

Subtitles (318 segments)

00:00

“Water. Earth. Fire. Air.” Aristotle may  not have had a poster of the periodic table

00:06

on his bedroom wall growing up.

00:08

But he sure did have an idea about  what everything on Earth was made of.

00:11

That idea was very, very wrong, of course,

00:13

even if it did help spawn a  beloved television series.

00:16

But over the following millennia,

00:18

scientists slowly worked things out.

00:20

By the time Dmitri Mendeleev published his  original version of the periodic table,

00:24

in 1869, there were 63  elements that scientists knew

00:27

made all the matter we can  see, touch, and so forth.

00:30

Part of that was thanks to  advances in scientific theory,

00:33

like Dalton’s concept of the atom.

00:35

Part of it was thanks to advances in  scientific methods and technology.

00:38

But the path from 63 to the current  118 elements was not straightforward.

00:42

In fact, there are many times scientists  thought they had discovered a new element,

00:46

but didn’t.

00:47

So many in fact, you could make  a SciShow List Show about it…

00:50

[intro jingle]

00:53

Here’s a lie that your teacher might  have told you when you were young:

00:55

“Sunlight is made up of all  the colours of the rainbow.”

00:58

And by “lie ”, I mean it’s so close to true

01:00

almost no one is going to call that teacher out.

01:03

Except for when it actually matters.

01:04

Like right now.

01:05

In the early 1800s,

01:07

the German glassmaker Joseph von Fraunhofer

01:09

split sunlight up into its constituent colors

01:12

using a device he invented called a spectroscope.

01:14

And he found 574 dark lines  in the otherwise full rainbow.

01:19

In other words, a bunch of colors were missing.

01:21

These lines turned out to be super important

01:23

for chemistry, physics, astronomy, and optics.

01:26

Fraunhofer’s discovery was,  and remains, a pretty big deal.

01:29

He was the first to document  these spectral absorption lines,

01:31

caused by atoms absorbing  specific amounts of energy

01:34

from light that’s passing through.

01:36

Because when you’re dealing with light,  energy corresponds to wavelength…

01:39

that is, color.

01:40

Then the 1860s, some other German scientists…

01:43

including Robert Wilhelm  Bunsen of “bunsen burner” fame…

01:46

found that absorption lines  had not-at-all-evil twins

01:49

called spectral emission lines

01:50

that show up when you split up  the light coming from an element

01:53

when it’s burning.

01:54

Both emission and absorption lines

01:56

are the result of an atom’s electrons  jumping between energy levels.

02:00

When it’s emission, the electron  is emitting that energy,

02:02

so it’s dropping down some number of levels.

02:05

When it’s absorption, it’s the opposite.

02:06

The exact amount of energy,

02:08

and therefore the exact color of the light,

02:10

depends on several factors, including  how many electrons are involved,

02:13

and which levels they’re jumping between.

02:14

Both of these lines act  like chemical fingerprints,

02:17

because each atom has a unique  set of lines that they produce.

02:20

So element hunters started using spectroscopes

02:22

to split light from all sorts of places

02:24

to find unique new fingerprints,  and therefore elements.

02:27

Remember that this is right around when Mendeleev

02:30

is coming up with his periodic table.

02:31

He’s arranged the known elements  according to atomic weight,

02:34

but he realised that there are  repeating patterns of properties.

02:36

When he mapped it all out,

02:37

there were actually gaps where  unknown elements might be.

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